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Contributions of heat and/or mass from mafic magmas are commonly invoked in models of voluminous granodiorite and andesite generation in magmatic and volcanic arcs worldwide. However, mafic intrusions are a volumetrically minor component in most arc batholiths. This is the case in the Sierra Nevada batholith, California, USA, where gabbro and diorite plutons are smaller and less abundant than the granitoid suites that make up the bulk of the batholith. Here, we constrain the timing and geochemistry of mafic intrusions in the Sierra Nevada batholith to assess the role of these compositions in arc batholith construction. Previous detailed studies on a limited number of mafic intrusions demonstrate that they formed penecontemporaneously with the felsic batholith, but there is a need for a broader survey of mafic plutons using modern geochronological techniques. New U-Pb zircon ages for 13 gabbro to diorite plutons and geochemistry from 17 mafic intrusions in the eastern Sierra Nevada batholith document two main episodes of mafic magmatism in the eastern Sierra Nevada batholith, from 168 Ma to 145 Ma and from 100 Ma to 89 Ma. These episodes overlap with the ages of granitoid plutons in the eastern Sierra Nevada batholith, including the Late Jurassic Palisade Crest and Late Cretaceous John Muir intrusive suites, in addition to other felsic plutons dated in the eastern Sierra Nevada batholith. Non-primitive mineral compositions in the mafic bodies indicate that their parental magmas are the evolved products of mantle-derived basalts that first differentiated in the lower crust prior to ascent and crystallization in the upper crust. The presence of rocks with cumulate textures, as well as a wide range of bulk-rock compositions (SiO2 wt% 38−64, Mg# 39−74), show that magmatic differentiation continued within each mafic body after intrusion into the upper crust. Sr/Y ratios in melt-like (i.e., non-cumulate) mafic samples suggest that the crustal thickness of the Sierra Nevada batholith was roughly 30 km in the Early Jurassic and increased to ∼44 km by the Late Cretaceous. Concomitant intrusion of mafic melts along with voluminous granitoid plutons supports mantle melting as a major contributor of heat and magmatic volumes to the crust during construction of the eastern Sierra Nevada batholith. 

Abstract The Fe3+/FeT ratios (Fe3+/[Fe2++Fe3+]) in minerals can be used to understand their crystallization and post-crystallization conditions. However, as natural minerals are often zoned and contain inclusions, bulk techniques, e.g., wet chemistry, may not provide accurate Fe3+/FeT values for a single phase of interest. We determined Fe3+/FeT ratios of amphiboles in different crystallographic orientations by single-crystal synchrotron Mössbauer spectroscopy (SMS) in energy and time domain modes from four volcanic localities (Long Valley Caldera, Mount St. Helens, Lassen Volcanic Center, U.S.A., and Mt. Pinatubo, Philippines). The high spatial resolution (as low as 12 × 12 μm spot size) and standard-free nature of SMS allow the detection of intra-grain compositional heterogeneities in Fe3+/FeT with relatively low uncertainties. We combine SMS with major element compositions, water contents, and hydrogen isotope compositions to document the Fe3+/FeT ratios as a function of mineral composition and post-crystallization dehydrogenation. Spectra were fitted with up to five distinct sites: ferrous iron on M(1), M(2), M(3), and ferric iron on M(2) and M(3), consistent with X-ray diffraction studies on single crystals of amphibole. The Fe3+/FeT ratios range from 0.14 ± 0.03 (Long Valley Caldera), 0.51 to 0.63 ± 0.02 (representing intra-grain heterogeneities, Mount St. Helens) to 0.86 ± 0.03 (Lassen Volcanic Center). The latter grain experienced post-crystallization dehydrogenation, shown by its low water content (0.6 ± 0.05 wt%) and its elevated hydrogen isotope composition (δD = +25 ± 3‰ relative to SMOW). The Fe3+/FeT ratios of 0.62 ± 0.01 and 0.20 ± 0.01 of two Mt. Pinatubo grains correlate with high-Al2O3 cores and low-Al2O3 rims and smaller phenocrysts in the sample, respectively. This study shows that SMS is capable of distinguishing two different domains with dissimilar Fe3+/FeT values formed under different crystallization conditions, demonstrating that SMS in combination with major element, water, and hydrogen isotope compositions allows the interpretation of amphibole Fe3+/FeT ratios in the context of crystallization and post-crystallization processes.